The former Lioness, 39, was in attendance at the 02 Arena as Jess presented an award.
Alex Scott wore a red dress to the Brit Awards Credit: Rex
She later changed her outfit as she headed to the after party alongside Jess Glynne Credit: Splash
The singer, 34, was on hand to present Raye with her Best R&B Act gong.
It was one of six awards that the 26-year-old scooped on a historic night.
Football Focus presenter Alex wore a burgundy red dress as she walked the red carpet.
She appeared alongside partner Jess, who wore a pink outfit.
Later in the night, the pair performed an outfit change each for the after party.
Alex changed into a white shirt and pinstripe blazer combo with a skirt and thigh-high boots.
Jess, meanwhile, wore a see-through outfit, but also donned a long pair of boots to complete her look.
The pair posed for snaps and shared a kiss together.
The Universal Music bash took place at 180 Studios in London.
Many stars that had attended the Brits partied long into the early hours.
Alex and Jess recently enjoyed a holiday in Mexico together.
The duo headed to the Tulum region, soaking up the sun while enjoying plenty of activities.
While away in Mexico they tried scuba diving and zip-lining.
The weather was a far-cry from what it'll be during an upcoming challenge, with Alex one of a number of celebrities set to trek the Arctic for Comic Relief.
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